Mechanical properties, elastic constants, lattice vibrations of Gallium Arsenide (GaAs)

GaAs - Gallium Arsenide

Mechanical properties, elastic constants, lattice vibrations

Basic Parameter
Elastic constants
Acoustic Wave Speeds
Phonon frequencies

Basic Parameter

Bulk modulus7.53·1011 dyn cm-2
Density5.317 g cm-3
Hardness on the Mohs scalebetween 4 and 5
Surface microhardness (using Knoop's pyramid test)750 kg mm-2
Cleavage plane{110}
Piezoelectric constante14=-0.16 C m-2

Elastic constants 300 K.

C11=11.90·1011 dyn/cm2
C12=5.34·1011 dyn/cm2
C44=5.96·1011 dyn/cm2

Temperature dependences of elastic constants.
For 0<T<Tm=1513K (in units of 1011 dyn cm-2)
C11= 12.17 - 1.44·10-3T
C12= 5.46 - 0.64·10-3T
C44= 6.16 - 0.70·10-3T
(Burenkov et al. [1973])

For T = 300 K

Bulk modulus (compressibility-1)Bs= 7.53·1011dyn/cm2
Shear modulusC'= 3.285·1011dyn/cm2
[100] Young's modulusYo= 8.59·1011dyn/cm2
[100] Poisson ratioσo = 0.31

Acoustic Wave Speeds

Wave
propagation
Direction
Wave
character
Expression for wave speedWave speed
(in units of
105 cm/s)
[100]VL(C11/ρ )1/24.73
VT(C44/ρ )1/23.35
[110]Vl[(C11+Cl2+2C44)/2ρ ]1/25.24
Vt||Vt||=VT=(C44/ρ)1/23.35
Vt⊥[(C11-C12)/2ρ]1/22.48
[111]Vl'[(C11+2C12+4C44)/3ρ]1/25.4
Vt'[(C11-C12+C44)/3ρ]1/22.8

Phonon frequencies

(in units of 1012 Hz) (Waugh and Dolling [1963])
νTO(Γ)8.02νLO (X)7.22
νLO(Γ)8.55νTA(L)1.86
νTA(X)2.36νLA(L)6.26
νLA(X)6.80νTO(L)7.84
νTO(X)7.56νLO(L)7.15